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A wide range of polymers based on other heterocyclic 5-membered rings have been investigated, including oxadiazole, pyrazole, triazole, tetrazole, and thiophene [Bass et al., 1987; Briffaud et al., 2001; Cassidy, 1980; Critchley et al., 1983; Gebben et al., 1988; Ueda and Sugita, 1988].

Classic Instruments Are Not Dead!

temporary war taxes. By 1959, these Dutch yields were roughly the same as the American yields and were far below English and French yields. After 1960, Dutch yields almost paralleled the huge rise in American yields to the mid-1970 s. From then until the end of the 1980s, Dutch yields were noticeably below American yields. The gap was quite large for the Dutch 31 4s shown in Chart 61 but was also present in the case of other Dutch yields. Short-Term Dutch Interest Rates. Dutch short-term interest rates are presented in Table 65 in two groups: (a) the discount rate of the Bank of the Netherlands in terms of annual average and range of fluctuation; and (b) the market rate of discount in Amsterdam, or the private discount rate, 1900 1912, 1915 1941, and the rate on three-month Treasury bills, 1945 1989, all in terms of annual average and annual high and low. The discount rate continued to be a penalty rate, as it was in the nineteenth century, and the open market rates often were below it; in easy-money periods they were far below it. These short rates are pictured in Chart 62. Short-term Dutch open market rates at the beginning of the twentieth century were rising. However, they were moderate, like other European short rates, and unlike American commercial paper rates, which were high. Aside from a flurry in 1906 1907, which also occurred in other countries, the Dutch open market rates stayed moderate until 1910. During World War I, in spite of an increase in the discount rate,

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2-14i 6-Membered Ring Heterocyclic Polymers Polyquinolines (PQ) are obtained by the Friedlander reaction of a bis-o-aminoaromatic aldehyde (or ketone) with an aromatic bisketomethylene reactant [Concilio et al., 2001; Stille, 1981]. The quinoline ring is formed by a combination of an aldol condensation and imine formation (Eq. 2-221). Polymerization is carried out at 135 C in m-cresol with poly (phosphoric acid) as the catalyst. The reaction also proceeds under base catalysis, but there

2-221

are more side reactions. There has been a considerable effort to use the reactive telechelic oligomer approach to producing crosslinking polyquinolines [Sutherline and Stille, 1986]. PQs in the repeating unit have been obtained by reactions other than the Friedlander reaction [Moore and Robello, 1986; Ruan and Litt, 1988]. Polyphenylquinoxalines (PPQ) are obtained by the polymerization of aromatic bis-odiamine and bis-a-ketoaldehyde reactants in m-cresol at $80 C [Hergenrother, 1988; Klein et al., 2001]:

which was finally pegged at 41 2%, the open market rate fell at one time to below 2%. In 1920, it rose only to 4.22% when the English open market rate rose above 6%. Clearly, short-term interest rates in the Dutch money market remained low, far below those of the belligerents. Dutch bond yields, in contrast, rose at their 1920 highs above 6%. The German inflation of 1920 1923 created few repercussions in the Dutch money market, which remained relatively stable in the 1920 s. Average rates were then at their highest since the 1860 s, but they were well below the English and French short-term rates. In the 1930 s, Dutch short rates declined sharply, as did short rates in other countries. They ran up sharply in 1935, and then declined to new lows. During World War II, Dutch short rates remained low. After the war and through the devaluation of 1949, the Dutch official discount rate was held at 21 2%, and open market rates were permitted to decline to around 1%. This resembled the postwar English policy of very low short-term rates and contrasted with rising short rates in France and in America. It was in the 1950 s that the Dutch money market contrasted most strikingly with other money markets. Short rates stayed low after a flurry in 1951 and rose only moderately in another flurry in 1956 1957. In 1957, the discount rate got up briefly to 5% when the British bank rate was at 7%. The Dutch bill rate averaged 3% when open market rates in Britain averaged 5% and those in France averaged over 6%. Soon after 1957, the Dutch open market rate declined again, to below 2%. Short open market Dutch rates averaged 1.72% in the 1950 s, when English

2-222

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