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That s right. The common instruments of the orchestra are living instruments, too. As they age, their voices change, but not, of course, on the time scale of living, circuit-bent instruments. In the world of acoustic instruments this is both good and bad. The upside of this predicament results in instruments that sound better over time as they age. Woodwind instruments claim this fortune. More famous, though, is the Stradivarius violin, whose mysterious lacquer, it is supposed, has strengthened and purified the instrument s tone over time.

Reaction temperatures above 100 C are avoided to prevent branching. PPQs can also be synthesized from monomers that contain the quinoxaline ring [Maier, 2001]. Most PQ and PPQ polymers are amorphous, although a few show some crystalline behavior. PQ and PPQ are promising materials as they possess a very good combination of properties: excellent thermal and oxidative stability, resistance to acids and bases, high glass transition temperature, and high strength and modulus. These properties are coupled with a signi cant ability to be processed. This is especially the case for PPQ polymers. There is a considerable range between the glass transition temperature and the decomposition temperature, which allows for thermoplastic processing. Also, PPQ is soluble in phenolic and chlorinated solvents, although PQ is soluble only in phenolic solvents. The favorable combination of properties has resulted in considerable efforts to explore the synthetic and practical limits of the PQ and PPQ systems. A number of ladder PQ and PPQ polymers have been studied, but the results have been disappointing, as is the case with other ladder polymers. Nonladder PQ and PPQ polymers in the form of lms, composites, and adhesives show good high-temperature properties, but their utilization is impeded by high costs. Many other 6-membered ring systems have been explored as the basis for hightemperature polymers, including anthrazoline, quinazolone, benzoxazinone, and s-triazine [Cassidy, 1980; Critchley et al., 1983].

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(continued)

2-14j Conjugated Polymers There has been a large effort to synthesize organic conjugated polymers [Aldissi, 1989; Fromer and Chance, 1986; Kraft et al., 1998; Maier, 2001; Potember et al., 1987; Pron

and Rannou, 2002; Yamamoto, 2002] because such polymers have potential as semiconducting, conducting, and light-emitting (optoelectronic) materials Organic polymers offer potential advantages over the traditional inorganic and nonpolymeric materials used for these purposes First, processing of organic conjugated polymers by molding and other plastics processing techniques into various electrical, electronic, and optoelectronic devices and forms is potentially easier and more economical compared to processes used for inorganic and nonpolymeric materials Second, the lightweight property of polymer materials would make certain types of applications more practical and economical One potential application for conjugated polymers is lightweight rechargeable batteries for portable devices and vehicles Conducting polymers would serve both current-carrying and ion conduction functions by replacing traditional electrode and electrolyte substances Another area of application for conducting polymers is their use in building circuitry elements, both passive (conducting circuits) and active (p n and Schottky junctions).

Other potential applications include transparent antistatic coatings for metals and electronic devices, electromagnetic shielding, light-emitting diodes (LEDs), electrodes, biosensors, transistors, and ultrathin, exible screens for computer and TV monitors The structural requirement for a conducting polymer is a conjugated p-electron system The typical polymers studied are based on a p-conjugated electron system constituting the polymer backbone, but conducting polymers are also possible when the p-conjugated electron system is present as side chains Polymers with conjugated p-electron systems display unusual electronic properties, including high electron af nities and low ionization potentials Such polymers are easily oxidized or reduced by charge-transfer agents (dopants) that act as electron acceptors or electron donors, respectively This could result in poly(radical cation)or poly(radical anion)-doped conducting materials (p-type and n-type, respectively) with near-metallic conductivity in some cases.

open market rates averaged above 3%, French open market rates averaged nearly 4%, and American commercial-paper rates averaged 258% Clearly, the Dutch were clinging to the advantages, such as they were, of low interest rates They were permitting their larger neighbors to resort to the weapon of tight money against the postwar inflation and thus help keep Dutch prices down Holland did not abandon its ancient tradition of low interest rates This policy was maintained into the 1960 s and, indeed, until inflation got out of hand in 1973 The Dutch decennial average for Treasury bills was 336% for the 1960 s, as compared to 397% in the United States, 490% in France, and 580% in England An annual average of 2% occurred as late as 1972 Then came the first oil price shock.

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